One-pot co-crystallized hexanal-loaded ZIF-8/quaternized chitosan film for temperature-responsive ethylene inhibition and climacteric fruit preservation.

Controlling ethylene production and microbial infection are key factors to prolong the shelf life of climacteric fruit. Herein, a nanocomposite film, hexanal-loaded ZIF-8/CS (HZCF) with "nano-barrier" structure, was developed by a one-pot co-crystallized of ZIF-8 in situ growth on quaternized chitosan (CS) and encapsulation of hexanal into ZIF-8 via microporous adsorption. The resultant film realized the temperature responsive release of hexanal via the steric hindrance and hierarchical pore structure as "nano-barrier", which can inhibit ethylene production in climacteric fruit on demand. Based on this, the maximum ethylene inhibition rate of HZCF was up to 52.6 %. Meanwhile, the film exhibits excellent antibacterial, mechanical, UV resistance and water retention properties, by virtue of the functional synergy between ZIF-8 and CS. Contributed to the multifunctional features, HZCF prolonged the shelf life of banana and mango for at least 16 days, which is 8 days longer than that of control fruit. More strikingly, HZCF is washable and biodegradable, which is expected to replace non-degradable plastic film. Thus, this study provides a convenient novel approach to simplify the encapsulation of active molecule on metal-organic frameworks (MOFs), develops a packaging material for high-efficient freshness preservation, and helps to alleviate the survival crisis caused by food waste.

Self-triggered carboxymethyl chitosan hydrogel for the convenient sustained release of ClO2 gas with environmental stability and long-term antimicrobial effect.

Challenges associated with the storage and uncontrolled release of ClO2 gas present significant hurdles to its practical application. Herein, a clever strategy for self-triggering the sustained release of chlorine dioxide (ClO2) gas is proposed by crosslinking carboxymethyl chitosan (CMCS) with Zn2+ to construct a novel CMCS-Zn@NaClO2 gel with eco-friendly, environmental stability, and convenient, long term, and efficient antibacterial activity. The precursor (NaClO2) in the CMCS solution was alkaline and triggered by the acidic Zn(NO3)2·6H2O solution to achieve sustained self-triggering ClO2 release. The ClO2 gas self-release could be sustained on demand at different temperatures for at least 20 days due to the environmental structure stability of the gel. The hydrogels showed an increase in pore size after sustained release. Molecular dynamics simulations showed the spontaneous release of ClO2 gas at room temperature and the contraction of the CMCS agglomeration, which were consistent with the macroscopic behaviour. The gel displayed a long-acting and high antibacterial efficacy, resulting in a bacteria-killing rate of over 99.9% (inhibitory concentrations of 2.5 mg mL-1 against E. coli and 0.16 mg mL-1 against S. aureus). The hydrogels could effectively extend the shelf life of fruits and demonstrated an excellent wide range of antibacterial properties. This work provides a new approach to solving the storage difficulty of ClO2 gas and offers a fresh perspective on the design of materials with convenient self-triggering release by a precursor, as well as the relationship between the material microstructure and sustained-release behaviour.